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Chemical Thermodynamics eBook, Notes Download
Rajan Sharma

Chemical Thermodynamics eBook, Notes Download

Rajan Sharma | 15-Feb-2016 |
Introduction , Single component systems , Multicomponent systems , The ideal solution model , Partial molar properties , Nonideal solutions , Stability , Solid-liquid equilibrium , Gas solubility and Henry’s law , Equations of state , Thermodynamics from equations of state , Chemical reaction equilibria , Introduction , Single component systems , Multicomponent systems , The ideal solution model , Partial molar properties , Nonideal solutions , Stability , Solid-liquid equilibrium , Gas solubility and Henry’s law , Equations of state , Thermodynamics from equations of state , Chemical reaction equilibria ,

Hi friends, here Rajan Sharma uploaded notes for Thermodynamics and Chemical Thermodynamics with title Chemical Thermodynamics eBook, Notes Download. You can download this lecture notes, ebook by clicking on the below file name or icon.

1 Introduction
1.1 Basic concepts
1.1.1 State function versus path function
1.1.2 Intensive property versus extensive property
1.2 Brief review of thermodynamics
1.2.1 The fi rst law of thermodynamics
1.2.2 The second law of thermodynamics
1.3 The fundamental equation of thermodynamics
1.4 The calculus of thermodynamics
1.5 Open systems
1.6 Legendre transforms and free energies
2 Single component systems
2.1 General phase behavior
2.2 Conditions for phase equilibrium
2.3 The Clapeyron equation

Contents
3 Multicomponent systems
3.1 Thermodynamics of multicomponent systems
3.1.1 The fundamental equation of thermodynamics
3.1.2 Phase equilibria
3.1.3 Gibbs phase rule
3.2 Binary mixtures
3.2.1 Vapor-liquid equilibrium
3.2.2 Liquid-liquid equilibria
3.2.3 Vapor-liquid-liquid equilibria
3.3 Ternary mixtures
4 The ideal solution model
4.1 Defi nition of the ideal solution model
4.2 Derivation of Raoult’s law
5 Partial molar properties
5.1 Defi nition
5.2 Relationship between total properties and partial molar properties
5.3 Properties changes on mixing
5.4 Graphical representation for binary systems

Contents
6 Nonideal solutions
6.1 Deviations from Raoult’s law and the activity coeffi cient
6.2 Modifi ed Raoult’s law
6.3 Empirical activity coeffi cient models
6.4 The Gibbs-Duhem equation
6.5 Azeotropic systems
7 Stability
7.1 Introduction
7.2 Liquid-liquid equilibrium
8 Solid-liquid equilibrium
8.1 Introduction
8.2 Phase behavior
8.3 Conditions for equilibrium
9 Gas solubility and Henry’s law
9.1 Henry’s law
9.2 Activity coeffi cients

Chemical Thermodynamics Contents
10 Equations of state
10.1 The principle of corresponding states
10.2 The van der Waals equation and cubic equations of state
10.3 Equations of state for mixtures
11 Thermodynamics from equations of state
11.1 The residual Helmholtz free energy
11.2 Fugacity
11.3 Vapor-liquid equilibrium with a non-ideal vapor phase
12 Chemical reaction equilibria
12.1 Conditions for equilibrium
12.2 The phase rule for chemically reacting systems
12.3 Gas phase reactions
12.4 The standard Gibbs free energy of formation
12.5 The infl uence of temperature
12.6 Liquid phase reactions
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